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Product Name: VS1003B-B/LSR-ROHS (BGA49 RoHS) References of “Threshold level” columns:
1) Report the biggest content rate (ppm) of the substance at the homogeneous material level. Optionally also the total weight of the substance in the product.
Weight = total weight of the substance in the product.
Content rate [ppm] = Content rate of the substance in the homogeneous material that has the biggest ppm content of the substance.
Example: Lead (Pb) content in lead frame plating [ppm] = weight of lead (Pb) in leadframe [10^-9 g] / weight of the leadframe [mg]
2) Report the total weight of the substance in the product. Optionally also content rate (ppm) of the substance at the product.
Weight = total weight of the substance in the product.
Content rate [ppm] = Content rate of the substance in the product.
Example: Bismuth weight = Sum of Bismuth weights in each homogeneous material.
3) Any content = Not contain obviously OR under quantitation limit of accurate analytical method.
NA) Not Applicable.
cust.A = Customer from Japan cust.B = Customer from USA
JIG-101, Material and Substance Declaration: Detailed Chemical list with CAS-numbers and other details of JIG-101: http://www.jedec.org/download/
Above threshold
Substance
R (Requlated) JIG Criteria 1
If yes (Y), detailed information of contained substances
Threshold
Level JIG cust.A cust.B
Category Name
Threshold Level – JIG
Threshold Level – cust.A
Level – cust.B (Y/N)
Additional information on material composition of products
See JIG-101 for detailed CAS#. Also CAS# 132207-32-0, 132207-33-1.
Must be reported only if it is used for leather/fabric products and those parts where they are likely to result in prolong skin contact. 30 ppm in finished Hexavalent Chromium / Hexavalent Chromium JIG: see Diarsenic Pentaoxide and Diarsenic Trioxide in SVHC list.
HFC and PFC. For JIG also SF6. See JIG-101 for detailed CAS-numbers.
cust.A = DE ChemVerbotsV, AT BGBI. Nr. 194/1990, SE KIFS 1998:8 (9,
20-27 §§) cust.B: Select 1 of fol owing: concentration in the air: 0.1 ppm
(EN 717-1:2004), or perforator method: 6.5 mg/100g particleboard, 7.0 mg/100g fiberboard (both average value during 6 months), 8.0 mg particle/fiberboard one time measurement based EN 120:1992. or Desiccators method: average content 0.5 mg/l, Maximum content 0.7 mg/l (use N = 2, JIS A 5905 (Fiberboards, JIS A 5908 Particleboards) see ”Brominated Flame Retardants (other than PBBs or PBDEs)” Above threshold
Substance
R (Requlated) JIG Criteria 1
If yes (Y), detailed information of contained substances
Threshold
Level JIG cust.A cust.B
Category Name
Threshold Level – JIG
Threshold Level – cust.A
Level – cust.B (Y/N)
Additional information on material composition of products
100 ppm (1) resin paint, ink pigment 500 ppm solder for children 12 years or younger purchasing pwd and components (1) 500 ppm lead free soldering except for 100 ppm other Use of nickel or nickel in components and parts designed to be located inside the outer enclosure of a product need not be reported. Cust.B = cust. A = EU 76/769/EEC, 30. amendment, Annex I, No. 52 Exemptions of
1 micrograms/m2 in textiles or coated or other coated use (only for cust. A and cust. B): a) photoresists or anti reflective coatings materials. 0.1 weight% (1000ppm) in materials 1 for photolithography processes b) photographic coatings applied to films, papers, or printing plates, c) mist suppressants for non-decorative hard chromium (VI) plating and wetting agents for use in control ed electroplating Phenol,2-(2H-benzotriazol-2-yl)- Intentional y added (1) CAS# 117-81-7, CAS# 84-74-2, CAS# 85-68-7 1000 ppm of plasticized material (childrens toy that can CAS# 28553-12-0, CAS# 68515-48-0, CAS# 26761-40-0, CAS# 68515-49- 1, CAS# 117-84-0 for cust A. and cust. B also DNHP CAS# 84-75-3 Also monobromodiphenyl (C12 H9 Br) included.
JIG includes also DecaBDE CAS# 1163-19-5, see detailed list in JIG-101.
JIG: TV and computer housings have lower Deca-BDE threshold level.
SCCP, CAS# 85535-84-8Also Tributyl tin bromide (CAS# 1461-23-0), Triphenyl tin (CAS# 668-34-8), Triphenyl tin bromide (C6 H5)3 Sn Br and Mixture of tributyl tin cyclopentanecarboxylate and its analogs (Tributyl tin naphthenate, CAS# Triphenyl Tin (TPT) compounds Intentional y added (1) JIG-101, Material and Substance Declaration: Detailed Chemical list with CAS-numbers and other details of JIG-101: http://www.jedec.org/download/
Above threshold
Substance
If yes (Y), detailed information of contained substances
Threshold
Level JIG cust.A cust.B
Category Name
Threshold Level – JIG
Threshold Level – cust.A
Level – cust.B (Y/N)
Additional information on material composition of products
Beryllium/Beryllium Compounds 1000 ppm (2) criteria 3 – I (for For JIG: reportable applications: ceramics cust.B: TBBP-A-bis (CAS# 21850-44-2), JIG: (other than PBBs or PBDEs or Hexabromocyclododecane(HBCDD)) see detailed list in JIG-101.
CAS# 115-96-8, reguirement from ECHA Registry of Intentions PFOS substances:
List of PFOS substances, list may not include al variations:
US EPA Significant New Use Rule 1:
http://www.epa.gov/EPA-TOX/2002/December/Day-09/t31011.htm
US EPA Significant New Use Rule 2 (which also include some PFAS molecules):
http://www.epa.gov/EPA-TOX/2007/October/Day-09/t19828.htm
JIG-101: Detailed Chemical list with CAS-numbers and other details see JIG-101 at http://www.jedec.org/download/
Additional Material and Substance Declarations:
Substance
Above threshold level ?
If yes (Y), detailed information of contained substances
Category Name
Threshold Level
Threshold Level – cust.B
Level (Y/N)
[ppm] Additional information on material composition of products
As for the service parts, the professional products, and the transportation parts, when the content exceeds 100ppm to less than 10000ppm display the text "Restricted to professional user" to the cobalt chloride inclusion quality wrapping. Directives of EU: 2003/34/EC, 98/98/EC and See also “Phthalates” in previous table of this document.
CAS# 2385-85-5. Prohibition of Certain Toxic Substances Regulations, 2005 (SOR/SOR/2005- 41. Published in Canada Gazette Part II, 2006-11-29 Vol. 140, No. 24 Halogenated diphenyl methanes Any content (3) JIG-101 (PCB+PCT) includes CAS# 76253-60-6, CAS# 99688-47-8 and Ugilec121, Ugilec 21.
Brominated dioxins/furans and Chlorinated dioxins/furans ChemVerbotsV, information source “2008 GADSL Version 2.0”Japan, Law Concerning the Examination and Regulation of Manufacture of Chemical Including Dibutyltin compounds. See also TBT, TPT and TBTO in one of the previous tables of Certain Glycol Ethers see list in use in manufacture of the end of this doc EU-D 67/548/EEC, information source “2008 GADSL Version 2.0”CAS# 624-49-7. If no intentional use is verified by tracing back through the supply chain, analysis for checking non-use of applicable substances is not required.
Red phosphorous CAS 7723-14-0 should not be used to substitute Brominated Flame Retradants due to historical industry experience with reliability concerns.
Semiconductor industry voluntary banned the use of certain ethylene glycol ethers in manufacture of semiconductors.
Certain Glycol Ethers
2-Ethoxyethanol (or Ethylene glycol monoethyl ether) 2-Methoxyethanol (or Ethylene glycol monomethyl ether) List of Substances of Very High Concern (SVHC) – page 1 of 2
http://echa.europa.eu/chem_data/candidate_list_table_en.asp
Substance
If yes (Y), detailed information of contained substances
Category Name
Threshold Level
Above threshold level ? Y / N
Weight [mg]
rate [ppm]
Additional information on material composition of products
EC Number: 427-700-2, CAS Number: 15606-95-8. Article 57(a) of Regulation (EC) 1907/2006 (REACH).
EC Number: 204-371-1 CAS Number: 120-12-7. PBT substance according to Article 57 (d) of Regulation (EC) No EC Number: 202-974-4 CAS number: 101-77-9. Article 57(a) of Regulation (EC) 1907/2006 (REACH).
EC Number: 201-557-4 CAS number: 84-74-2. Article 57 (c) of Regulation (EC) 1907/2006 (REACH).
EC number: 231-589-4 CAS number: 7646-79-9. Carcinogenic and toxic for reproduction (articles 57 a and 57 c) EC Number: 215-116-9 CAS number: 1303-28-2. Article 57 (a) of Regulation (EC) No 1907/2006 (REACH).
EC Number: 215-481-4 CAS number: 1327-53-3. Article 57 (a) of Regulation (EC) No 1907/2006 (REACH).
EC number: 234-190-3 CAS number: 10588-01-9 (anhydrous) 7789-12-0 (dihydrate). Article 57(a), (b) and (c) of EC Number: 201-329-4 CAS number: 81-15-2. Article 57(e) of Regulation (EC) No 1907/2006 (REACH).
EC Number: 204-211-0 CAS number: 117-81-7. Article 57 (c) of Regulation (EC) 1907/2006 (REACH).
EC Number: 221-695-9, 247-148-4 CAS number: 3194-55-6, 25637-99-4 Names of the major diastereoisomers identified: alpha-hexabromocyclododecane CAS No 134237-50-6 beta-hexabromocyclododecane CAS No 134237- 51-7 gamma-hexabromocyclododecane CAS No 134237-52-8. Article 57 (d) of Regulation (EC) No 1907/2006 EC Number: 287-476-5 CAS number: 85535-84-8. Article 57 (d and e) of Regulation (EC) No 1907/2006 (REACH).
EC Number: 200-268-0 CAS number: 56-35-9. Article 57 (d) of Regulation (EC) No 1907/2006 (REACH).
EC Number: 232-064-2 CAS number: 7784-40-9. Article 57 (a and c) of Regulation (EC) No 1907/2006 (REACH).
EC Number: 201-622-7 CAS number: 85-68-7. Article 57 (c) of Regulation (EC) 1907/2006 (REACH).
EC number: 204-450-0 CAS# 121-14-2, Carcinogenic (article 57a) Carcinogenic (article 57a). Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017- 00-8 in Annex VI, part 3, table 3.2 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, label ing and packaging of substances and mixtures, and fulfil the two fol owing conditions: a) Al2O3 and SiO2 are present within the fol owing concentration ranges: a1) Al2O3: 43.5 – 47 % w/w, and SiO2: 49.5 – 53.5 % w/w, OR a2) Al2O3: 45.5 – 50.5 % w/w, and SiO2: 48.5 – 54 % w/w, b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm).
EC number: 292-602-7 CAS# 90640-80-5. Carcinogenic (see Detail 1) below the table), PBT and vPvB (articles EC number:292-604-8 CAS# 90640-82-7. Carcinogenic (see Detail 2), mutagenic (see Detail 3 below the table), PBT and vPvB (articles 57a, 57b, 57d and 57e) EC number:292-603-2 CAS# 90640-81-6. Carcinogenic (see Detail 2), mutagenic (see Detail 3 below the table), PBT and vPvB (articles 57a, 57b, 57d and 57e) EC number: 295-275-9 CAS# 91995-15-2. Carcinogenic (see Detail 2), mutagenic (see Detail 3 below the table), PBT and vPvB (articles 57a, 57b, 57d and 57e) EC number: 295-278-5 CAS#91995-17-4. Carcinogenic (see Detail 2), mutagenic (see Detail 3 below the table), PBT and vPvB (articles 57a, 57b, 57d and 57e) EC number: 201-553-2 CAS# 84-69-5. Toxic for reproduction (article 57c) EC number: 231-846-0 CAS# 7758-97-6. Carcinogenic and toxic for reproduction (articles 57a and c) Detail 1) The substance does not meet the criteria for identification as a carcinogen in situations where it contains less than 0.005 % (w/w) benzo[a]pyrene (EINECS No 200-028-5) Detail 2) The substance does not meet the criteria for identification as a carcinogen in situations where it contains less than 0.005 % (w/w) benzo[a]pyrene (EINECS No 200-028-5) and less than 0,1 % w/w benzene (EINECS No 200-753-7).
Detail 3) The substance does not meet the criteria for identification as a mutagen in situations where it contains less than 0,1 % w/w benzene (EINECS No 200-753-7).
List of Substances of Very High Concern (SVHC) – page 2 of 2
Substance
If yes (Y), detailed information of contained substances
Category Name
Threshold Level
Above threshold level ? Y / N
Weight [mg]
rate [ppm]
Additional information on material composition of products
Lead chromate molybdate sulphate red (C.I. Pigment Red EC number: 235-759-9 CAS# 12656-85-8. Carcinogenic and toxic for reproduction (articles 57a and c) EC number: 215-693-7 CAS# 1344-37-2. Carcinogenic and toxic for reproduction (articles 57a and c) EC number: 266-028-2 CAS# 65996-93-2. Carcinogenic, PBT and vPvB (articles 57a, 57d and 57e) EC number: 204-118-5 CAS# 115-96-8. Toxic for reproduction (article 57c) Carcinogenic (article 57a).Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.2 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, label ing and packaging of substances and mixtures, and fulfil the two fol owing conditions: a) Al2O3, SiO2 and ZrO2 are present within the fol owing concentration ranges: a1) Al2O3: 35 – 36 % w/w, and a2) SiO2: 47.5 – 50 % w/w, and a3) ZrO2: 15 - 17 % w/w, b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm).
EC number: 201-173-7 CAS# 79-06-1. Carcinogenic and mutagenic (articles 57 a and 57 b) EC number: 201-167-4 CAS# 79-01-6. Carcinogenic (article 57 a) EC number: 233-139-2 / 234-343-4 CAS# 10043-35-3 / 11113-50-1. Toxic for reproduction (article 57 c) EC number: 215-540-4 CAS#1303-96-4/ 1330-43-4/ 12179-04-3. Toxic for reproduction (article 57 c) EC number: 235-541-3 CAS# 12267-73-1. Toxic for reproduction (article 57 c) EC number: 231-906-6 CAS# 7778-50-9. Carcinogenic, mutagenic and toxic for reproduction (articles 57 a, 57 b EC number: 232-143-1 CAS# 7789-09-5. Carcinogenic, mutagenic and toxic for reproduction (articles 57 a, 57 b and EC number: 232-140-5 CAS# 7789-00-6. Carcinogenic and mutagenic (articles 57 a and 57 b).
EC number: 231-889-5 CAS# 7775-11-3. Carcinogenic, mutagenic and toxic for reproduction (articles 57 a, 57 b EC number: 233-334-2 CAS# 10124-43-3. Carcinogenic and toxic for reproduction (articles 57 a and 57 c) EC number: 233-402-1 CAS# 10141-05-6 . Carcinogenic and toxic for reproduction (articles 57 a and 57 c) EC number: 208-169-4 CAS# 513-79-1. Carcinogenic and toxic for reproduction (articles 57 a and 57 c) EC number: 200-755-8 CAS# 71-48-7. Carcinogenic and toxic for reproduction (articles 57 a and 57 c) EC number: 203-713-7 CAS# 109-86-4. Toxic for reproduction (article 57c) EC number: 203-804-1 CAS# 110-80-5. Toxic for reproduction (article 57c) EC number: 215-607-8 CAS# 1333-82-0. Carcinogenic and mutagenic (articles 57 a and 57 b) chromic acid and dichromic acid, c) Dichromic acid EC number: a) 231-801-5 b) - c) 236-881-5 CAS# a) 7738-94-5 b) – c) 13530-68-2. Carcinogenic (article 57a) EC Number: 203-839-2 CAS number: 111-15-9. Toxic for reproduction (article 57c) EC Number: 232-142-6 CAS number: 7789-06-2. Carcinogenic (article 57a) 1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters EC Number: 271-084-6 CAS number: 68515-42-4. Toxic for reproduction (article 57c) EC Number: 206-114-9 CAS number: 302-01-2 / 7803-57-8. Carcinogenic (article 57a) EC Number: 212-828-1 CAS number: 872-50-4. Toxic for reproduction (article 57c) EC Number: 202-486-1 CAS number: 96-18-4. Carcinogenic and toxic for reproduction (articles 57 a and 57 c).
1,2-Benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich EC Number: 276-158-1 CAS number: 71888-89-6. Toxic for reproduction (article 57c) Detail 1) The substance does not meet the criteria for identification as a carcinogen in situations where it contains less than 0.005 % (w/w) benzo[a]pyrene (EINECS No 200-028-5) Detail 2) The substance does not meet the criteria for identification as a carcinogen in situations where it contains less than 0.005 % (w/w) benzo[a]pyrene (EINECS No 200-028-5) and less than 0,1 % w/w benzene (EINECS No 200-753-7).
Detail 3) The substance does not meet the criteria for identification as a mutagen in situations where it contains less than 0,1 % w/w benzene (EINECS No 200-753-7).
A) Changes due to JIG–101 Ed 2.0:- LEVEL A and B replaced by criteria 1 – R Regulated (R), criteria 2 – A (for assesment only) and criteria 3 – I (for information only) - Minor changes: JIG Asbestos, threshold level changed from "Any content (2 and 3)" to "Intentional y added".
JIG: Beryllium and Beryllium compounds, only Beryllium Oxide included. Cust.A and Cust.B requirements include al Beryllium and Beryllium compounds.
JIG: Brominated flame retradants exclude Hexabromocyclododecane(HBCDD), because it is separated to SVHC list.
JIG: requirement of Arsenic/Arsenic compaunds covers only Diarsenic Pentaoxide and Diarsenic Trioxide JIG: Cadmium threshold level changed from 75ppm to 100ppm, 5ppm threshold level added for battery.
JIG: requirements for Formaldehyde added.
JIG: new reguirements for Lead/lead compounds.
JIG: Mercury/mercury compounds, reguirement added for battery.
JIG: Nickel, threshold level changed form ”0.5 micrograms/sq cm/week” to ”Intentional y added” JIG: Ozone Depleting Substances, threshold level changed from ”Any content (2 and 3)” to ” Intentional y added” JIG: requirements for PFOS added.
JIG: requirements for Certain Phthalates more detailed (see Phthalates) JIG: extra requirement for Deca-BDE (see PBDE) JIG: Shortchain Chlorinated Paraffins (C10 – C13), threshold level changed from ”1000 ppm or Intentional y Added (1)” to ”1000 ppm (2)” JIG: Tributyl Tin Oxide (TBTO), threshold level changed from ”Intentional y Added (2)” to ”1000 ppm or Intentional y Added (2)” JIG: Antimony, Bismuth and Selenium reguirements removed from JIG. - Added new substances: JIG: Fluorinated greenhouse gases JIG: Perchlorates JIG: Phenol,2-(2H-benzotriazol-2-yl)-4,6-bis(1, 1-dimethylethyl) CAS# 3846-71-7 JIG: Tris (2-chloroethyl) phosphate (TCEP)B) Changes due list of SVHC 13.1.2010: 14 substances added (last 14 on the table) C) No changes to cust.A and cust.B requirements.
D) Lead/lead compounds RoHS excemption items removed.
A) Changes due to JIG–101: no changes.
B) Changes due list of SVHC 15.12.2010: 17 substances added (last 17 on the table) C) No changes to cust.A and cust.B requirements.
A) Changes to “Additional Material and Substance Declarations” table:Comment added for Organic tin compunds: “Including Dibutyltin compounds.”New requlated substance added “Dimethyl fumarate (DMF)” A) Changes due to JIG–101: no changes.
B) Changes due list of SVHC 20.6.2011: 7 substances added (last 7 on the table) and more details added for Cobalt Dichloride.
C) No changes to cust.A and cust.B requirements.

Source: http://www.vlsi.fi/fileadmin/quality/material_declaration_files/VS1003B_BGA49_RoHS_MaterialDeclaration_rev_1_7.pdf