PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 1 of 9 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME PERMATEX BEARING MOUNT FOR RELAXED FITS PROPER SHIPPING NAME ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(contains 2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane) PRODUCT USE Anaerobic bearing mount adhesive for repairing worn machinery parts. SUPPLIER Company: ITW Polymers & Fluids Address: 100 Hassall Street Wetherill Park NSW, 2164 Australia Telephone: +61 2 9757 8800 Emergency Tel: 1800 039 008 Emergency Tel: +61 3 9573 3112 Fax: +61 2 9757 3855 Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only. RISK Risk Codes
• Irritating to respiratory system and skin.
• May cause SENSITISATION by skin contact.
• Very toxic to aquatic organisms, may cause long- termadverse effects in the aquatic environment. SAFETY Safety Codes
• Do not breathe gas/fumes/vapour/spray.
• Wear suitable protective clothing.
• Use only in well ventilated areas.
• Keep container in a well ventilated place.
• Avoid exposure - obtain special instructions before use.
• To clean the floor and all objects contaminated by this material, use waterand detergent.
• This material and its container must be disposed of in a safe way.
• Keep away from food, drink and animal feeding stuffs.
• In case of contact with eyes, rinse with plenty of water and contact Doctor orPoisons Information Centre.
• If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (showthis container or label).
• Use appropriate container to avoid environmental contamination.
• Avoid release to the environment. Refer to special instructions/Safety datasheets.
• This material and its container must be disposed of as hazardous waste.
• In case of accident by inhalation: remove casualty to fresh air and keep atrest. continued. PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 2 of 9 Section 2 - HAZARDS IDENTIFICATION Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
2, 2- bis[4- (2- methacryloxy)ethoxy)phenyl]propane
bisphenol A/ propylene oxide/ fumarate copolymer
Section 4 - FIRST AID MEASURES SWALLOWED • If swallowed do NOT induce vomiting. • If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. • Observe the patient carefully. • Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. EYE ■If this product comes in contact with the eyes: • Immediately hold eyelids apart and flush the eye continuously with running water. • Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. • Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. • Transport to hospital or doctor without delay. SKIN ■If skin contact occurs: • Immediately remove all contaminated clothing, including footwear. • Flush skin and hair with running water (and soap if available). • Seek medical attention in event of irritation. INHALED • If fumes or combustion products are inhaled remove from contaminated area. • Lay patient down. Keep warm and rested. • Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. • Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. NOTES TO PHYSICIAN ■Treat symptomatically. Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA • Foam. • Dry chemical powder. • BCF (where regulations permit). • Carbon dioxide. FIRE FIGHTING • Alert Fire Brigade and tell them location and nature of hazard. • May be violently or explosively reactive. • Wear full body protective clothing with breathing apparatus. • Prevent, by any means available, spillage from entering drains or water course. FIRE/EXPLOSION HAZARD • Combustible. • Slight fire hazard when exposed to heat or flame. • Heating may cause expansion or decomposition leading to violent rupture of containers. • On combustion, may emit toxic fumes of carbon monoxide (CO). Combustion products include: carbon dioxide (CO2), aldehydes, hydrogen chloride, phosgene, nitrogen oxides (NOx), other pyrolysis continued. PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 3 of 9 Section 5 - FIRE FIGHTING MEASURES
products typical of burning organic material. May emit clouds of acrid smoke. WARNING: Long standing in contact with air and light may result in the formationof potentially explosive peroxides. FIRE INCOMPATIBILITY • Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may HAZCHEM •3Z Section 6 - ACCIDENTAL RELEASE MEASURES MINOR SPILLS ■Environmental hazard - contain spillage. • Clean up all spills immediately. • Avoid breathing vapours and contact with skin and eyes. • Control personal contact by using protective equipment. • Contain and absorb spill with sand, earth, inert material or vermiculite. MAJOR SPILLS ■Environmental hazard - contain spillage. • Absorb or contain isothiazolinone liquid spills with sand, earth, inert material or vermiculite. • The absorbent (and surface soil to a depth sufficient to remove all of the biocide) should be shovelled into a drum and treated
with an 11% solution of sodium metabisulfite (Na2S2O5) or sodium bisulfite (NaHSO3), or 12% sodium sulfite (Na2SO3) and 8%hydrochloric acid (HCl).
• Glutathione has also been used to inactivate the isothiazolinones. • Use 20 volumes of decontaminating solution for each volume of biocide, and let containers stand for at least 30 minutes to
deactivate microbicide before disposal.
• DO NOT touch the spill material. Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING • DO NOT allow clothing wet with material to stay in contact with skin. • Avoid all personal contact, including inhalation. • Wear protective clothing when risk of exposure occurs. • Use in a well-ventilated area. • Prevent concentration in hollows and sumps. SUITABLE CONTAINER • Metal can or drum • Packaging as recommended by manufacturer. • Check all containers are clearly labelled and free from leaks. STORAGE INCOMPATIBILITY • Polymerisation may occur slowly at room temperature. • Storage requires stabilising inhibitor content and dissolved oxygen content to be monitored. Refer to manufacturer's recommended levels. • DO NOT overfill containers so as to maintain free head space above product. • Blanketing or sparging with nitrogen or oxygen free gas will deactivate stabiliser. • Store below 38 deg. C. • Contamination with polymerisation catalysts - peroxides, persulfates, oxidising agents - also strong acids, strong alkalies, will cause polymerisation with exotherm - generation of heat. • Polymerisation of large quantities may be violent - even explosive. STORAGE REQUIREMENTS • WARNING: Decomposition may occur after prolonged storage. • Polymerisation may occur slowly at room temperature. • Storage requires stabilising inhibitor content and dissolved oxygen content to be monitored. Refer to manufacturer's recommended levels. • DO NOT overfill containers so as to maintain free head space above product. • Blanketing or sparging with nitrogen or oxygen free gas will deactivate stabiliser. continued. PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 4 of 9 Section 7 - HANDLING AND STORAGE
Rotate all stock to prevent ageing. Use on FIFO (First In-First Out) basis. • Store below 38 deg. C. • Store in original containers. • Keep containers securely sealed. • No smoking, naked lights or ignition sources. • Store in a cool, dry, well-ventilated area. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS The following materials had no OELs on our records • 2, 2- bis[4- (2- methacryloxy)ethoxy)phenyl]propane:
• bisphenol A/ propylene oxide/ fumarate copolymer:
MATERIAL DATA 2,2-BIS[4-(2-METHACRYLOXY)ETHOXY)PHENYL]PROPANE: 2-HYDROXYPROPYL METHACRYLATE: SACCHARIN:
â– Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat.
Historically occupational exposure standards for these irritants have been based on observation of workers' responses to variousairborne concentrations.
BISPHENOL A/ PROPYLENE OXIDE/ FUMARATE COPOLYMER:SACCHARIN:
â– It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there
is evidence of health effects at airborne concentrations encountered in the workplace.
At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal
experiments or clinical experience).
NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply.
â– None assigned. Refer to individual constituents.
2,2-BIS[4-(2-METHACRYLOXY)ETHOXY)PHENYL]PROPANE:
â– CEL TWA: 1 mg/m3 [compare WEEL-TWA* for multifunctional acrylates (MFAs)]Exposure to MFAs has been reported to cause contact dermatitis in humans and serious eye injury in laboratory animals.
Exposure to some MFA-resin containing aerosols has also been reported to cause dermatitis.
â– For cumyl hydroperoxide:CEL TWA: 1 ppm, 6 mg/m3 (SKIN) (compare WEEL TWA)Saturated vapour concentration: 2632 ppm at 20 C. Cumene hydroperoxide is severely irritating to the eyes and skin and is moderately toxic by ingestion, inhalation and dermal
For cumene:Odour Threshold Value: 0.008-0.132 ppm (detection), 0.047 ppm (recognition)Exposure at or below the TLV-TWA is thought to prevent induction of narcosis. For acetophenone:Odour Threshold Value: 0.17 ppmAcetophenone produces narcosis and anaesthesia when swallowed or injected intravenously or subcutaneously. Contact with the
skin produces irritation and, if confined, may burn.
Acute inhalation studies indicate that a saturated atmosphere (nominally 400 ppm) produced no fatalities in rats exposed for 8
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin. Absorption by skin
may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes andmucous membranes may also contribute to overall exposure and may also invalidate the exposure standard.
■CEL TWA: 0.1 mg/m3; STEL 0.3 mg/m3 total isothiazolinones (Rohm and Haas). continued. PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 5 of 9 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECTION RESPIRATOR •Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) EYE • Safety glasses with side shields. • Chemical goggles. • Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]. HANDS/FEET ■NOTE: • The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other
protective equipment, to avoid all possible skin contact.
• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. • Butyl rubber gloves. • Nitrile rubber gloves. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexterity. General warning: Do NOT use latex gloves! Use only recommended gloves - using the wrong gloves may increase the risk:
Exposure condition Short time use; (few minutes
Use of thin nitrile rubber gloves: Nitrile
less than 0.5 hour) Little physical stress
rubber (0.1 mm) Excellent tactibility (" feel"), powder- free Disposable Inexpensive Giveadequate protection to low molecular weighacrylic monomers
Exposure condition Medium time use; less than 4
Use of medium thick nitrile rubber gloves
hours Physical stress (opening drums, using
Nitrile rubber, NRL (latex) free; <0.45 mm
Moderate tactibility (" feel" ), powder- freeDisposable Moderate price Gives adequateprotection for most acrylates up to 4 hours DoNOT give adequate protection to low molecularweight monomers at exposures longer than 1 hour
Nitrile rubber, NRL (latex) free; >0.56 mm low
tactibility (" feel" ), powder free High priceGives adequate protection for most acrylates incombination with commonly used solvents up to 8hours Do NOT give adequate protection to lowmolecular weight monomers at exposures longerthan 1 hour Avoid use of ketones and acetatesin wash- up solutions. OTHER • Overalls. • P.V.C. apron. • Barrier cream. • Skin cleansing cream. ENGINEERING CONTROLS ■Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. CARE: Use of a quantity of this material in confined space or poorly ventilated area, where rapid build up of concentrated atmosphere may occur, could require increased ventilation and/or protective gear. continued. PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 6 of 9 Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Green liquid with a sharp odour; partially miscible with water. PHYSICAL PROPERTIES Liquid. Section 10 - STABILITY AND REACTIVITY CONDITIONS CONTRIBUTING TO INSTABILITY • Polymerisation may occur at elevated temperatures. • Polymerisation may be accompanied by generation of heat as exotherm. • Process is self accelerating as heating causes more rapid polymerisation. • Exotherm may cause boiling with generation of acrid, toxic and flammable vapour. For incompatible materials - refer to Section 7 - Handling and Storage. Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED ■Accidental ingestion of the material may be damaging to the health of the individual. Ingestion may result in nausea, abdominal irritation, pain and vomiting. EYE ■If applied to the eyes, this material causes severe eye damage. SKIN ■This material can cause inflammation of the skin oncontact in some persons. The material may accentuate any pre-existing dermatitis condition. The material is a vesicant causing blistering on contact. Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. INHALED ■Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful. The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage. Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of co-ordination, and vertigo. Inhalation hazard is increased at higher temperatures. Acute effects from inhalation of high vapour concentrations may be chest and nasal irritation with coughing, sneezing, headache and even nausea. CHRONIC HEALTH EFFECTS ■Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. continued. PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 7 of 9 Section 11 - TOXICOLOGICAL INFORMATION
There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared tothe general population. Based on experience with similar materials, there is a possibility that exposure to the material may reduce fertility in humansat levels which do not cause other toxic effects. Sensitisation may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitised persons should not beallowed to work in situations where exposure may occur. TOXICITY AND IRRITATION â– Not available. Refer to individual constituents. CARCINOGEN Saccharin and its
International Agency for Research on Cancer
to Group 3 withsupporting evidencefrom other relevantdata)
Section 12 - ECOLOGICAL INFORMATION
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ safety data sheets. Ecotoxicity Ingredient Section 13 - DISPOSAL CONSIDERATIONS
• Recycle wherever possible or consult manufacturer for recycling options. • Consult State Land Waste Authority for disposal. • Bury or incinerate residue at an approved site. • Recycle containers if possible, or dispose of in an authorised landfill. Section 14 - TRANSPORTATION INFORMATION M I S C E L L A N E O U S D A N G E R O U S ■Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082are not subject to this Code when transported by road or rail in;(a) packagings;(b) IBCs; or(c) any other receptacle not exceeding 500 kg(L). - Australian Special Provisions (SP AU01) - ADG Code 7th Ed. Labels Required: MISCELLANEOUS
continued. PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 8 of 9 Section 14 - TRANSPORTATION INFORMATION HAZCHEM: •3Z ADG7: Class or Division:
Name and Description: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains 2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane)
Land Transport UNDG: Class or division:
Shipping Name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains 2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane)
Air Transport IATA: ICAO/IATA Class:
Shipping name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(contains 2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane)
Maritime Transport IMDG: IMDG Class:
Shipping name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(contains 2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane)
Section 15 - REGULATORY INFORMATION REGULATIONS Regulations for ingredients 2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane (CAS: 24448-20-2) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)" 2-hydroxypropyl methacrylate (CAS: 923-26-2,27813-02-1) is found on the following regulatory lists; "Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)" bisphenol A/ propylene oxide/ fumarate copolymer (CAS: 39382-25-7) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)" cumyl hydroperoxide (CAS: 80-15-9) is found on the following regulatory lists; "Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2","Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","International Council of Chemical Associations (ICCA) - High Production Volume List" saccharin (CAS: 81-07-2) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)","International Fragrance Association (IFRA) Survey: Transparency List" No data for Permatex Bearing Mount for Worn Parts (CW: 30-0602) continued. PERMATEX BEARING MOUNT FOR RELAXED FITS Chemwatch Independent Material Safety Data Sheet Issue Date: 30-Jan-2012 CHEMWATCH 30-0602 Version No:2.0 CD 2011/4 Page 9 of 9 Section 16 - OTHER INFORMATION Denmark Advisory list for selfclassification of dangerous substances Substance INGREDIENTS WITH MULTIPLE CAS NUMBERS Ingredient Name
â– Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
â– The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 30-Jan-2012Print Date: 30-Jan-2012
Responsibility in Counselling Supervision in New Zealand: An Exploratory Study of Supervisor Perspectives Kathie Crocket, Desmond Cooper, John Crockett, Jill Elder, Paul Flanagan, PeterHoride, Susan Mortlock, Glen Silvester, Wendy Talbot, Carol White Abstract This study investigated how experienced supervisors understand the matter of supervisor responsibility, and the effects of that underst