Material Safety Data Sheet DRAGNET® SFR TERMITICIDE/INSECTICIDE SDS # : 1784-A Revision Date: 2011-07-25 Version 1
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This MSDS has been prepared to meet U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200
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1. PRODUCT AND COMPANY IDENTIFICATION Product name Formula code Active Ingredient(s) Alternate Commercial Name Synonyms
FMC 33297; 3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate;(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
Chemical Family Recommended use Manufacturer Emergency telephone number
FMC CorporationAgricultural Products Group
+1 (651) 632-6793 (All Other Countries - Collect)
For leak, fire, spill or accident emergencies, call:
+1 703 / 527 3887 (CHEMTREC - Collect - All Other Countries)
2. Hazards identification Appearance Physical state Physical or Chemical Hazards Flammable properties Potential health effects Acute effects Inhalation
Inhalation of vapors in high concentration may cause irritation of respiratory system. May causedrowsiness and dizziness. DRAGNET® SFR TERMITICIDE/INSECTICIDE MSDS #: 1784-A Revision Date: 2011-07-25 Version 1 Ingestion
Harmful if swallowed. Potential for aspiration if swallowed. May cause drowsiness and dizziness. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic effects
May cause adverse kidney effects. May cause adverse liver effects. 3. Composition/information on ingredients Hazardous ingredients Chemical Name
Petroleum distillates, hydrotreated light
4. First aid measures
Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses,if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctorfor further treatment advice.
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificialrespiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor forfurther treatment advice.
Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by apoison control center or doctor. Do not give any liquid to the person. Do not induce vomiting or giveanything by mouth to an unconscious person.
Contains petroleum distillate. Vomiting may cause aspiration pneumonia. This product is apyrethroid. If large amounts have been ingested, the stomach and intestines should be evacuated. Treatment is symptomatic and supportive. Digestible fats, oils, or alcohol may increase absorptionand so should be avoided. 5. Fire-fighting measures Flammable properties Flash Point Sensitivity to Mechanical Impact Sensitivity to Static Discharge Suitable extinguishing media
Foam. Carbon dioxide (CO ). Dry chemical. Water spray or fog. Protective equipment and precautions
As in any fire, wear self-contained breathing apparatus and full protective gear. Isolate fire area. for firefighters Health Hazard Flammability Stability Special Hazards 6. Accidental release measures DRAGNET® SFR TERMITICIDE/INSECTICIDE MSDS #: 1784-A Revision Date: 2011-07-25 Version 1 Personal precautions
Isolate and post spill area. Wear suitable protective clothing, gloves and eye/face protection. Forpersonal protection see section 8. Environmental precautions
Keep people and animals away from and upwind of spill/leak. Keep material out of lakes, streams,ponds, and sewer drains. Methods for cleaning up
Sweep up and shovel into suitable containers for disposal. Clean and neutralize spill area, tools andequipment by washing with bleach water and soap. Absorb rinsate and add to the collected waste. Waste must be classified and labeled prior to recycling or disposal. Dispose of waste as indicated inSection 13.
For further clean-up instructions call FMC Emergency Hotline number listed in Section 1 "Productand Company Identification" above. 7. Handling and storage Handling
Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.
Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sourcesof ignition. Keep out of reach of children and animals. Store in original container only. 8. Exposure controls/personal protection Exposure guidelines Chemical Name British Columbia Ontario TWAEV Occupational exposure controls Engineering measures
Apply technical measures to comply with the occupational exposure limits. Ensure adequateventilation, especially in confined areas. When working in confined spaces (tanks, containers, etc.),ensure that there is a supply of air suitable for breathing and wear the recommended equipment. Personal Protective Equipment General Information
If the product is used in mixtures, it is recommended that you contact the appropriate protectiveequipment suppliers, These recommendations apply to the product as supplied
Respiratory protection
For dust, splash, mist or spray exposures wear full-face elastomeric half mask respirator withappropriate cartridges and/or filters, which is approved for pesticides (U.S. NIOSH/MSHA, EU CENor comparable certification organization). Eye/face protection
For dust, splash, mist or spray exposure, wear chemical protective goggles or a face-shield
Skin and body protection
Wear long-sleeved shirt, long pants, socks, shoes, and gloves. Hand protection DRAGNET® SFR TERMITICIDE/INSECTICIDE MSDS #: 1784-A Revision Date: 2011-07-25 Version 1 Hygiene measures
Clean water should be available for washing in case of eye or skin contamination. Wash skin prior toeating, drinking, chewing gum or using tobacco. Shower or bathe at the end of working. Remove andwash contaminated clothing before re-use. Launder work clothing separately from regular householdlaundry. 9. Physical and chemical properties Appearance Physical state Melting Point/Range Freezing point Boiling Point/Range Flash Point
66-68 - 68 °C / 151-154 °F Tag Closed Cup
Evaporation rate Autoignition Temperature Flammable properties Vapor pressure Vapor density Specific Gravity Water solubility Percent volatile Partition coefficient: Viscosity Oxidizing properties 10. Stability and reactivity Stability Conditions to avoid
Excessive heat, Extreme risk of explosion by shock, friction, fire or other sources of ignition
Hazardous decomposition products
Chlorine, Hydrogen chloride, Carbon oxides, Aldehydes. Hazardous polymerization 11. Toxicological information Eye contact Skin contact Ingestion
Large toxic doses of the formulated product, administered to laboratory animals, have producedcentral nervous system effects with symptoms that include hypersensitivity to touch and sound,tremors, and clonic convulsions. Vomiting after ingestion of this product may cause aspiration ofaromatic hydrocarbons into the lungs, which may result in fatal pulmonary edema. Inhalation
In animals overexposure has produced symptoms such as squinting eyes, irregular and rattlingbreathing, and ataxia. Inhalation of hydrocarbon vapors may cause headaches, dizziness,disturbances in vision, drowsiness, respiratory irritation, anesthesia, unconsciousness, and othercentral nervous system effects. > 2,000 mg/kg (rabbit)
LD50 Oral LC50 Inhalation: Sensitization
May cause sensitization of susceptible persons. DRAGNET® SFR TERMITICIDE/INSECTICIDE MSDS #: 1784-A Revision Date: 2011-07-25 Version 1 Chronic Toxicity - Other Ingredient(s) Chronic Toxicity
May cause adverse kidney effects. May cause adverse liver effects. Carcinogenicity
Not recognized as carcinogenic by Research Agencies (IARC, NTP, OSHA, ACGIH). Mutagenicity
Permethrin: Did not show mutagenic effects in animal experiments. Reproductive toxicity
Permethrin: No toxicity to reproduction. Neurological Effects
Permethrin: Clinical signs of neurotoxicity include altered motor activity and FOB effects, with nosigns of histopathology
Developmental Toxicity
Permethrin: Not teratogenic in animal studies
Target Organ Effects
Permethrin: Long-term feeding studies in animals resulted in increased liver and kidney weights,induction of the liver microsomal drug metabolizing enzyme system and histopathological changesin the lungs and liver. Chronic Toxicity - Other Ingredient(s)
Chronic exposure to aromatic hydrocarbons may cause headaches, dizziness, loss of sensations orfeelings (such as numbness), and liver and kidney damage. 12. Ecological information Marine pollutant Ecotoxicity Permethrin (52645-53-1) Active Ingredient(s) Duration Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates
promelas 96 h LC50 2.2 mg/LLepomis macrochirus 96 hLC50 2.4 mg/L Oncorhynchusmykiss 96 h
Environmental Fate Permethrin (52645-53-1) Active Ingredient(s) Type of Test
Bioconcentration factor (BCF), Bluefill sunfish
DRAGNET® SFR TERMITICIDE/INSECTICIDE MSDS #: 1784-A Revision Date: 2011-07-25 Version 1
Stable to hydrolysis over a wide range of pHvalues. 13. Disposal considerations Waste disposal methods
Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate isprohibited. If these wastes cannot be disposed of by use according to label instructions, contactappropriate disposal authorities for guidance. Contaminated packaging
Containers must be disposed of in accordance with local, state and federal regulations. Refer to theproduct label for container disposal instructions. 14. Transport information
Not regulated for transportation if shipped in Non Bulk packaging. The classification below pertainsto the shipment in Bulk packaging. Packaging Type Proper shipping name Hazard Class Packing group Marine pollutant Proper shipping name
Environmentally hazardous substance, liquid, n.o. s. Hazard Class Packing group ICAO/IATA Proper shipping name
Environmentally hazardous substance, liquid, n.o. s. Hazard Class Packing group Marine pollutant Description
Environmentally hazardous substance, liquid, n.o.s. (permethrin), UN3082 + Marine Pollutant
Limited quantity IMDG/IMO Proper shipping name
Environmentally hazardous substance, liquid, n.o. s. Hazard Class Packing group Marine pollutant Description
Environmentally hazardous substance, liquid, n.o.s. (permethrin), UN3082 + Marine Pollutant
15. Regulatory information U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 DRAGNET® SFR TERMITICIDE/INSECTICIDE MSDS #: 1784-A Revision Date: 2011-07-25 Version 1 Chemical Name SARA 313 - Threshold Values SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Chemical Name U.S. - TSCA (Toxic Substances Control Act) - Section 8(a) - Chemical-Specific Reporting and Recordkeeping
Petroleum distillates, hydrotreated light
Partially exempt chemical substance termed Petroleum Process Stream
Chemical Name U.S. - TSCA (Toxic Substances Control Act) - Section 8(d) - 716.120(a) - Health and Safety Reporting - List of Substances International Regulations Mexico - Grade Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class 16. Other information Revision Date: Reason for revision: Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. , Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. , Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By DRAGNET® SFR TERMITICIDE/INSECTICIDE MSDS #: 1784-A Revision Date: 2011-07-25 Version 1
FMC Logo and Dragnet - Trademarks of FMC Corporation
2012 FMC Corporation. All Rights Reserved. End of Material Safety Data Sheet
COMPARATIF DES LISTES 2004 et 2005 DE SUBSTANCES ET PROCEDES INTERDITS LISTE 2004 MODIFICATIONS CONTENUES DANS LA LISTE 2005 (Arrêté du 20 avril 2004 modifié par l’arrêté du 16 août 2004) Classes des substances interdites en compétition Substances S1. Stimulants La classe S1 a comprend les substances interdites suivantes, ainsi que leurs interdites Adra
Dit artikel is oorspronkelijk verschenen als een interne publicatie op Epilepsiecentrum Kempenhaeghe, Heeze, Nederland in: de Ruif, 5, nr.1, pp. 17-22, november 1996. Toevoegingen na vertaling in het engels, Versie: 1.1, April 1998. Versie 1.2 met toevoegingen over behandelingsstrategieën, November 2001. Versie 1.3 met toevoeging van PGB, Juni 2003 Versie 1.4 met toevoegingen over QEEG, me