Safety Data Sheet acording to 1907/2006/EC, Article 31 1:1 CLEAR COAT VOC/S 1. Identification of the substance / mixture and of the company / undertaking Product identifier Trade name:1:1 CLEAR COAT VOC/S Relevant identified uses of the substance or mixture and uses advised against: Not determined Application of the substance / the preparation: Paint Details of the supplier of the safety data sheet Manufacturer / Supplier: Chemical Alliance Polska Sp. z o. o. ul. Prosta 23, Łozienica72-100 GoleniówPhone: +48 91 41 65 440 Fax: +48 91 41 65 487 firstname.lastname@example.orgFurther information obtainable from: Abteilung Labor +48 91 41 65 email@example.comEmergency telephone number: Phone: +48 784 020 firstname.lastname@example.org. Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC Xi Irritant R 43 May cause sensitisation by skin contact. R 10 Flammable. R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 66 Repeated exposure may cause skin dryness or cracking. R 67 Vapours may cause drowsiness and dizziness.Information concerning particular hazards for human and environmental: Vapours of product are heavier than air and may accumulate on the ground, in mines, drains or cellars with higher concentration. Heightened risk of fire and danger of explosion at accumulation in lower-lying or closed rooms. Contact with skin and inhalation of aerosols/ vapours of the preparation should be avoided. At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent. Has a narcotizing effect. The product has to be labeled due to the calculation procedure of the “General Classification guideline for preparations of the EU” in the latest valid version. ….Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives/ Ordinance on Hazardous MaterialsCode letter and hazard designation of product: Xi Irritant Risk phrases: May cause sensitisation by skin contact. R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 66 Repeated exposure may cause skin dryness or cracking.Vapours may cause drowsiness and dizziness.Safety Data Sheet acording to 1907/2006/EC, Article 31 1:1 CLEAR COAT VOC/S Safety phrases: S 36/37 Wear suitable protective clothing and gloves. S 51Use only in well ventilated areas. Avoid release to the environment. Refer to special instructions/safety data sheetHazard-determining components of labelling: tetraethyl N,N’-(methylenedicyclohexane-4,1-diyl)bis-dl-aspartate….Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. 3. Composition / information on ingredients Chemical characterization: Mixtures Description: Mixture of substance listed below with nonhazardous additions. Dangerous components: CAS: 136210-30-5 tetraethyl N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate Skin Sens. 1, H317; Aquatic Chronic 3, H412Flam. Liq. 3, H226; STOT SE 3, H336solvent naphtha (petroleum), light arom. Xn, Xi, N; R 10-37-51/53-65-66-67…. Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 2, H411; STOT SE 3, H335+H33601-2119463267-34-0001 Flam. Liq. 3, H226bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate Xi, N; R 43-50/53…. Skin Sens. 1, H317; Aquatic Acute 1, H400; Aquatic Chronic 1, H410methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacateXi, N; R 43-50/53…. Skin Sens. 1, H317; Aquatic Acute 1, H400; Aquatic Chronic 1, H410A mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)- 0,1-1 %5-(1,1-dimethylethyl)-4-hydroxyphenyl]propionatesAdditional information: For the wording of the listed risk phrases refer to section 16. Safety Data Sheet acording to 1907/2006/EC, Article 31 1:1 CLEAR COAT VOC/S 4. First aid measures Description of first aid measures General information: Personal protection for the First Aider. Take affected persons out of danger area and lay down. In case of irregular breathing or respiratory arrest provide artificial respiration. Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.After inhalation: Supply fresh air or oxygen, call for doctor. In case of unconsciousness place patient stably in side position for transportation.After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. Use skin protection cream for skin protection.After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.After swallowing: Rinse out mouth and than drink plenty of water. Do not induce vomiting: call for medical immediately.Most important symptoms and effects, both acute and delayed No further relevant information available.Indication of any immediate medical attention and special treatment needed The workplace should be equipped with a shower and eye wash position.5. Firefighting measures Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger with water spray or alcohol resistant foam.For safety reasons unsuitable extinguishing agents: Water with full jet. Special hazards arising from the substance or mixture Carbon monoxide and carbon dioxide. During heating or in case of fire poisonous gases are produced. Can form explosive gas-air mixtures.Advice for firefighters Protective equipment: Wear self-contained respiratory protective devices. Wear full protective suit. Additional information: Cool endangered receptacles with water spray. Remove undamaged containers from the danger zone. Collect contaminated fire fighting water separately. It must not enter the sewage system. Dispose of fire debris and contaminated fire fighting water in accordance with official regulation.6. Accidental release measures Personal precautions, protective equipment and emergency procedures Person-related safety precautions: Wear protective equipment. Keep unprotected person away. Ensure adequate ventilation. Keep away from ignition sources. Use respiratory protective device against the effects of fumes/dust/aerosol. Avoid contact with the eyes and skin.Environmental precautions Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system.Methods and material for containment and cleaning up Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Do not seal receptacle gas tight. Danger of bursting. Dispose of the material collected according to regulations.Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.Safety Data Sheet acording to 1907/2006/EC, Article 31 1:1 CLEAR COAT VOC/S 7. Handling and storage Precautions for safe handling Ensure good ventilation/ exhaustion at the workplace. Do not inhale gases/ fumes/ aerosols. Avoid contact with the eyes and skin. Use respiratory protective device against the effects of fumes/dust/aerosol. Adhere to the workplace limit values and / or other threshold values. Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).Information about fire- and explosion protector: Vapours of the product are heavier than air and may accumulate on the ground, in mines, drains or cellars with higher concentration. Fumes can combine with air to from an explosive mixture. Fumes can combine with air to form an explosive mixture. Flammable gas-air mixtures may form in empty receptacles. Keep ignition sources away - Do not smoke. Anti-explosion protection required. Protect against electrostatic charges.Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store only in original receptacle. Adhere to the provisions of the Low on Water Protection.Information about storage in use common storage facility: Store away from foodstuffs. Pls. refer to section 10Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. Store receptacle in a well ventilated areas. Protect from humidity and water. Keep ignition sources away - Do not smoke.Specific end use(s) No further relevant information available.8. Exposure controls / personal protection Additional information about design of technical facilities. No further data: see item 7 Control parameters Ingredients with limit values that require monitoring at the workplace: 123-86-4 n-butyl acetate WEL (Great Britain) Short-term value: 966 mg/m3, 200 ppm Long-term value: 724 mg/m3, 150 ppm108-65-6 2-methoxy-1-methylethyl acetate WEL (Great Britain) Short-term value: 548 mg/m3, 100 ppm Long-term value: 274 mg/m3, 50 ppmSkShort-term value: 550 mg/m3, 100 ppmLong-term value: 275 mg/m3, 50 ppmSkinAdditional information: The lists valid during the making were used as basis. tetraethyl N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate DNEL - workers, long-term - dermal, systemic effects - 4 mg/kg bm/24h DNEL - workers, long-term - inhalation, systemic effects - 28 mg/m3 PNEC - freshwater environment - 0,00013 mg/l PNEC - marine environment - 0,000013 mg/l PNEC - freshwater sediment environment - 0,21 mg/kg PNEC - marine sediment environment - 0,02 mg/l PNEC - sewage treatment plants - 31,1 mg/l PNEC - soil - 0,1 mg/kg n-butyl acetate DNEL - workers, long-term - dermal - 7 mg/kg bm/24h DNEL - workers, long-term - inhalation - 48 mg/m3 PNEC - freshwater environment - 0,18 mg/l PNEC - marine environment - 0,018 mg/l PNEC - intermittent releases - 0,36 mg/l PNEC - sewage treatment plants - 35,6 mg/l PNEC - freshwater sediment environment - 0,981 mg/kg PNEC - marine sediment environment - 0,981 mg/l PNEC - soil - 0,0903 mg/kg Safety Data Sheet acording to 1907/2006/EC, Article 31 1:1 CLEAR COAT VOC/S 2-methoxy-1-methylethyl acetate: DNEL - workers, long-term - inhalation, systemic effects - 275 mg/m3 DNEL - workers, long-term - dermal, systemic effects - 153,5 mg/kg bm PNEC - freshwater environment - 0,635 mg/l PNEC - freshwater sediment environment - 3,29 mg/l PNEC - marine sediment environment - 0,329 mg/l PNEC - soil 0,29 mg/kg PNEC - sewage treatment plants - 100 mg/l ethyl 3-ethoxypropionate DNEL - workers, long-term - dermal, systemic effects - 102 mg/kg bm/dayDNEL - workers, long-term - inhalation, systemic effects - 610 mg/m3DNEL - workers, long-term - dermal, local effects - 102 mg/cm2DNEL - workers, long-term - inhalation, local effects - 610 mg/m3PNEC - freshwater environment - 0,0609 mg/lPNEC - marine environment - 0,00609 mg/lPNEC - intermittent releases - 0,609 mg/lPNEC - sewage treatment plants - 50 mg/lPNEC - freshwater sediment environment - 0,419 mg/kgPNEC - marine sediment environment - 0,0419 mg/kgPNEC - soil - 0,048 mg/kgExposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Do not eat, drink, smoke or sniff while working. Do not inhale gases/ fumes/ aerosols. Avoid contact with the eyes and skin. Wash hands before breaks and at and the end of work. Respiratory protection: Adhere to the workplace limit values and / or other threshold values. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or larger exposures use self-contained respiratory protection device. Filter A/P2Protection of hands: To avoid skin problems reduce the wearing of gloves to the required minimum. Check the permeability prior to each anewed use of the gloves. The glove material has to be impermeable and resistant to the product / the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Wear suitable gloves tested to EN 374.Material of gloves: Laminate glove - PE/EVAL/PEThe selection of the suitable gloves does not only depend on the material but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application.Penetration time of glove material Value for the permeation: Level 6( ≥ 480 min). The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.Eye protection: Tightly sealed goggles Body protection: Protective work clothing. 9. Physical and chemical properties Information on basic physical and chemical properties Appearance Form: Color: Odour Odour threshold pH Melting point/ freezing point Initial boiling point and boiling range Undetermined Flash point Safety Data Sheet acording to 1907/2006/EC, Article 31 1:1 CLEAR COAT VOC/S Evaporation rate Flammability Upper/lower flammability or explosive limits Lower: Upper: Vapour pressure Vapour density Relative density Solubility(ies) Not miscible or difficult to mix in water.Partition coefficient: n-octanol/water Undetermined Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Product is not explosive. However, formation of explosive air/ vapour mixtures is possibleOxidising properties Other information 10. Stability and reactivity Reactivity No reactivity if used according to specifications.Chemical stability Stable under normal conditions of use and storage.Possibility of hazardous reactions Fumes can combine with air to form an explosive mixture.Conditions to avoid High temperature, ignition sources, open flame.Incompatible materials Oxidizing agents, alcohols, amines, aqueous acids and alkalis.Hazardous decomposition products Carbon monoxide and carbon dioxide. Formation of toxic gases is possible during heating or in case of fire.11. Toxicological information Information on toxicological effects Acute toxicity: LD/ LC50 values relevant for classification: 136210-30-5 tetraethyl N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate Oral 123-86-4 n-butyl acetate Oral Primary irritant effect: On the skin: Irritant to skin and mucous membranes. Repeated exposure may cause skin dryness or cracking. On the eye: Irritating effect. Additional toxicological information: Vapours may cause drowsiness and dizziness. Has a narcotizing effect. Sensitisation: Sensitisation possible through skin contact. 12. Ecological information Toxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Do not allow product to reach ground water, water course or sewage system.Persistence and degradability Safety Data Sheet acording to 1907/2006/EC, Article 31 1:1 CLEAR COAT VOC/S tetraethyl N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate - not inherently biodegradable n-butyl acetate - readily biodegradable2-methoxy-1-methylethyl acetate - readily biodegradablea mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4 hydroxyphenyl]propionates - not readily biodegradableBioaccumulative potential Octanol-water partition coefficient (Kow) tetraethyl N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate: 5,16 n-butyl acetate: 2,3 2-methoxy-1-methylethyl acetate: 0,43 A mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4 hydroxyphenyl]propionates: 9,2 Bioconcentration factor (BCF) tetraethyl N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate: BCF = 1872 n-butyl acetate: BCF =15,3 Mobility in soil No further relevant information available.Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Other adverse effects No further relevant information available.13. Disposal considerations Waste treatment methods Recommendation Must not to disposal together with household garbage. Do not allow product to reach sewage system. Disposal was be made according to official regulations.European waste catalogue 08 01 11* waste paint and varnish containing organic solvents or other dangerous substancesUncleaned packaging Recommendation: Disposal must be made according to official regulations. 14. Transport information UN-Number: 1263 UN proper shipping name: 1263 PAINT Transport hazard class(es): 3 Packaging group: III Hazard label: 3 Environmental hazards: The product does not pose a risk to the environment in accordance with the criteria in the UN Model Regulations. Special precautions for user: Warning: Flammable liquids. Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable. 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations: Information about limitation of use: Employment restrictions concerning juveniles must be observedEmployment restrictions concerning pregnant and lactating women must be observed.Safety Data Sheet acording to 1907/2006/EC, Article 31 1:1 CLEAR COAT VOC/S Chemical safety assessment: A Chemical Safety Assessment has been carried out for tetraethyl N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate n-butyl acetate2-methoxy-1-methylethyl acetate.16. Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.Relevant R-phrases: May cause sensitisation by skin contact.R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 65Harmful: may cause lung damage if swallowed.Repeated exposure may cause skin dryness or cracking.Vapours may cause drowsiness and dizziness.May be fatal if swallowed and enters airways.May cause an allergic skin reaction.May cause drowsiness or dizziness.Very toxic to aquatic life with long lasting effects.Toxic to aquatic life with long lasting effects.Harmful to aquatic life with long lasting effects.
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